I'm assuming you've got two route-maps where ACL 101 applies to the first route-map and ACL 102 to the second.
It would greatly help if you provided the whole Route-Map configuration, so we can clearly understand your setup.
As a general rule-of-thumb, you need to keep in mind that we use the permit statements for the traffic we do NOT want to route through the router's default route (Dialer interface/Internet). In your case, the permit statement would be used for the RDP/Printing traffic.
Keep in mind that the DENY statement will explicitly route traffic via the default-route, however there is always an explicit (invisible) DENY at the end of every access-list, so you do not need to make use of the DENY statement it unless you really need to.
A typical example for the use of the DENY statement is the following example:
Route the whole 192.168.1.0/24 subnet via the second router except host 192.168.1.10 - which would translate to the following commands:
access-list 101 deny ip host 192.168.1.10 any
access-list 101 permit ip 192.168.1.0 0.0.0.255 any
You can also check the following article that contains route-map and ACL configuration and can help provide an insight to your problem:
Configuring Policy-Based Routing (PBR) with IP SLA Tracking - Auto Redirecting Traffic
We are planning to cover ACLs and Route-maps extensively, so I'd suggest you sign up for newsletter updates if you haven't disabled this feature in your Firewall.cx account.
Let us know if you need anything else.